Alchemist Worldwide Ltd

Bilgi

Material Safety Data Sheet: Bis[3-(Triethoxysilyl)Propyl]Amine

Identification

Chemical Name: Bis[3-(Triethoxysilyl)Propyl]Amine
Synonyms: N-[3-(Triethoxysilyl)propyl]-3-(triethoxysilyl)-1-propanamine
CAS Number: 1760-24-3
EC Number: 217-164-6
Recommended Use: Industrial application, silane coupling agent
Manufacturer Information: Chemical supplier contact information available on request
Emergency Contact: Refer to company’s 24-hour emergency hotline

Hazard Identification

Classification: Eye irritation Category 2, Skin irritation Category 2, Specific Target Organ Toxicity—Single Exposure Category 3 (respiratory tract irritation)
Label Elements (GHS): Warning, exclamation mark pictogram
Hazard Statements: Causes skin irritation, causes serious eye irritation, may cause respiratory irritation
Precautionary Statements: Avoid breathing vapors/mist, use only outdoors or in well-ventilated area, wear protective gloves and eye protection, wash hands after handling
Signal Word: Warning
Potential Health Effects: Contact may lead to redness, swelling, or itching on skin. Breathing vapors in high concentration can cause dizziness and respiratory discomfort. Prolonged exposure underscores concern for cumulative effects on skin and eyes.
Environmental Hazards: Product may pose risks to aquatic environments in concentrated spills.

Composition / Information on Ingredients

Substance: Bis[3-(Triethoxysilyl)Propyl]Amine
CAS Number: 1760-24-3
EC Number: 217-164-6
Purity: >97%
Impurities: Contains trace amounts of ethanol by hydrolysis, no significant hazardous impurities

First Aid Measures

Inhalation: Remove person to fresh air without delay. If breathing is difficult, trained personnel may give oxygen. Seek medical attention if breathing remains affected.
Skin Contact: Take off contaminated clothing and shoes. Rinse skin immediately with plenty of water for at least 15 minutes. Use soap for thorough cleaning. See healthcare provider if irritation persists.
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Get medical advice if discomfort continues.
Ingestion: Rinse mouth with water. Never give anything by mouth to an unconscious person. Do not induce vomiting. Seek medical attention without delay.

Fire-Fighting Measures

Suitable Extinguishing Media: Alcohol-resistant foam, carbon dioxide, dry chemical powder, or water spray.
Unsuitable Extinguishing Media: Avoid high volume water jet.
Special Hazards: Flammable vapors may form in confined, unventilated concentrations. Heating can release irritating and potentially toxic gases such as oxides of nitrogen, silicon oxides, and carbon oxides.
Protective Equipment: Firefighters wear self-contained breathing apparatus and full protective suit.
Fire Fighting Instructions: Move containers from fire area if almost safe. Use water spray to keep unopened containers cool.

Accidental Release Measures

Personal Precautions: Use engineered ventilation to minimize vapor build-up. Wear chemical-resistant gloves, goggles, and impervious clothing. Evacuate unprotected people from spill area.
Environmental Precautions: Prevent release into sewers, drains, soil, and waterways.
Clean-up Methods: Contain spilled liquid with sand or earth. Collect in suitable, labeled containers for proper disposal. Wash area with soap and water. Ventilate spill area well.

Handling and Storage

Precautions for Safe Handling: Avoid contact with skin, eyes, and clothing. Work in a fume hood or well-ventilated environment. Do not breathe vapors or mists. Remove contaminated clothing before entering eating areas.
Storage Conditions: Store in tightly closed containers in a cool, dry, well-ventilated place. Keep away from heat, sparks, open flames, and sources of ignition. Segregate from acids, oxidizers, and moisture.
Incompatible Materials: Water, moisture, strong acids, and strong oxidizing agents.
Special Handling Notes: Use clean, dedicated equipment. Practice good industrial hygiene by cleaning up spills immediately.

Exposure Controls and Personal Protection

Exposure Limits: No official occupational exposure limits for Bis[3-(Triethoxysilyl)Propyl]Amine
Engineering Controls: Use local exhaust or process enclosure where possible. Avoid generating vapors.
Personal Protective Equipment:
Eye Protection: Chemical splash goggles or face shield
Hand Protection: Nitrile, neoprene, or butyl rubber gloves
Skin Protection: Lab coat or chemical resistant coveralls
Respiratory Protection: Use NIOSH-approved organic vapor respirator under conditions where airborne concentrations are high
Hygiene Measures: Wash hands before breaks and after handling, do not eat or drink in work area

Physical and Chemical Properties

Appearance: Clear to yellowish liquid
Odor: Aminic, slightly alcoholic
Odor Threshold: Not established
pH: Not available; hydrolyzes in water
Melting Point/Freezing Point: <–60°C
Boiling Point/Range: 334°C at 1 atm
Flash Point: 162°C (closed cup method)
Evaporation Rate: Not determined
Flammability: Not classified as flammable liquid
Vapor Pressure: <0.001 mmHg at 20°C
Vapor Density: Not available
Relative Density: 0.99–1.03 g/cm³ @ 20°C
Solubility: Insoluble in water, reacts slowly to produce ethanol and silanols
Partition Coefficient (n-octanol/water): Not available
Auto-Ignition Temperature: 280°C
Decomposition Temperature: Not determined
Viscosity: 19–25 mPa·s at 25°C

Stability and Reactivity

Chemical Stability: Stable under recommended storage temperatures/conditions.
Possibility of Hazardous Reactions: Moisture initiates slow hydrolysis, releasing ethanol. Reaction with strong oxidizers may generate exothermic conditions.
Incompatible Materials: Water, moisture, acids, oxidizing agents. Mixing with water causes hydrolysis and potential for pressure build-up in sealed containers.
Hazardous Decomposition Products: Silicon oxides, nitrogen oxides, carbon oxides, ethanol vapor.
Conditions to Avoid: Heat, flames, sparks, moisture.

Toxicological Information

Acute Toxicity Data: Oral LD₅₀ (rat): >2000 mg/kg; Dermal LD₅₀ (rabbit): >2000 mg/kg
Skin Corrosion/Irritation: Known to cause moderate irritation from primary skin contact
Serious Eye Damage/Irritation: May result in conjunctival redness, pain, and temporary blurred vision
Respiratory or Skin Sensitization: No data on respiratory sensitization; skin sensitization reported uncommonly
Germ Cell Mutagenicity: Not classified based on available studies
Carcinogenicity: No evidence linking to cancer in publicly available animal studies
Reproductive Toxicity: No specific hazard identified for reproduction or fetal toxicity
Specific Target Organ Toxicity: Single exposure may cause respiratory tract irritation
Aspiration Hazard: Data not sufficient, substance’s viscosity offers low aspiration risk
Chronic Effects: Prolonged skin or inhalation exposure can increase risk for irritation or inflammation

Ecological Information

Ecotoxicity: Acute aquatic toxicity considered low, limited chronic data available
Persistence and Degradability: Undergoes slow hydrolysis in water to low molecular weight silanols and ethanol
Bioaccumulative Potential: Not found to bioaccumulate based on chemical properties and predicted behavior
Mobility in Soil: Moderate mobility in soil, breakdown products more mobile than parent
Other Adverse Effects: Discharge of large quantities may affect water quality; attention required for chronic low-level releases

Disposal Considerations

Disposal Methods: Treat as hazardous chemical waste. Incinerate in properly permitted facility or use licensed chemical disposal service.
Container Disposal: Empty containers carry product residue; puncture and triple rinse before recycling or landfill. Do not reuse containers for other materials.
Special Precautions: Follow all federal, state, and local laws regarding chemical waste. Minimize environmental release.

Transport Information

UN Number: Not regulated as dangerous good in transport
Proper Shipping Name: Bis[3-(Triethoxysilyl)Propyl]Amine
Transport Hazard Class: Not classified as hazardous
Packing Group: Not applicable
Marine Pollutant: No
Certifications: Confirm packaging compatibility and shipping conditions with latest IATA, IMDG, ADR guidelines for non-hazardous chemicals.

Regulatory Information

TSCA (US): Listed
EINECS/ELINCS (EU): Listed
DSL/NDSL (Canada): Listed
REACH Status (EU): Requires registration or confirmation of compliance
Safety, Health, Environmental Regulations Specific to the Substance: Subject to workplace hazard communication standards, community right-to-know laws, and chemical control rules in most industrial countries. Follow applicable occupational environmental exposure standards.
Other Regulatory Notes: Product safety information sheets, workplace label requirements, and risk management procedures apply in industrial settings.